babytiger4852 babytiger4852
  • 14-02-2024
  • Chemistry
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Highest oxidation state of manganese in fluoride is +4 (MnF4) but highest oxidation state in oxides is +7 (Mn2O7) because:

i) Fluorine is more electronegative than oxygen.
ii) Fluorine does not possess d-orbitals.
iii) Fluorine stabilizes lower oxidation state.
iv) In covalent compounds, fluorine can form single bonds only while oxygen forms double bonds.

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