sondrascott166 sondrascott166
  • 13-01-2020
  • Chemistry
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What is the pH of a buffer solution that is 0.59 M pyridine and 0.30 M pyridinium bromide? (Assume the value of Kw is 1.0 10-14.)

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maacastrobr
maacastrobr maacastrobr
  • 14-01-2020

Answer:

pH = 5.54

Explanation:

We can think of the pyridinium cation as a weak acid (of pKa 5.25), and of pyridine as its conjugate base. As such, we can use the Henderson-Hasselbach equation to solve this problem:

pH = pKa + log ( [Pyridine]/[Pyridinium] )

pH = 5.25 + log (0.59/0.30)

pH = 5.25 + 0.29

pH = 5.54

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